270139 VO Chemistry of solution equilibria (2010S)

Brief descriptions of the topics:
- basic definitions of complex formation equilibrium processes; -experimental determination of proton dissociation and stability constants of metal complexes by different methods: pH-potentiometry, UV-Vis spectrophotometry; -evaluation of experimental data: from graphical methods to computer evaluation; -calculation of concentration distribution curves; -factors determining the compositions and stabilities of metal complexes; -determination of binding constants of non-metal complexes (e.g. protein-ligand) from different experimental data such as spectrofluorimetry, ultrafiltration, capillary electrophoresis etc.